Capsaicinoids
The potent active ingredient, considered early as a single substance,
"Capsaicin" was soon shown to be a mixture of two unsaturated and three
saturated homologs. This mixture is now called Capsaicinoids. The pungent components of
Capsicum annum include at least 5 compounds, known as Capsaicinoids:
| Name |
Code |
Systematic
Name |
| Capsaicin |
C |
trans-8-methyl-N-vanillyl-6-nonenamide |
| Dihydrocapsaicin |
DHC |
8-methyl-N-vanillyl-nonamide |
| Nordihydrocapsaicin |
NDHC |
7-methyl-N-vanillyl-octamide |
| Homodihydrocapsaicin |
HDHC |
9-methyl-N-vanillyl-decamide |
| Homocapsaicin |
HC |
trans-9-methyl-N-vanillyl-7-decenamide |
Capsaicinoids are produced by glands in the peppers placenta, which is the top of
the partition just below the stem. The placenta is about 16 times more pungent than the
flesh.
There are several other ingredients in Capsicum that directly
regulate the effectiveness of an OC formulation. One such ingredient is the pigment or the
"Carotinoid" also called "Capsanthin" with a molecular formula of
C40H56O3, and systematic name of
(3R,3S,5R)-3,3'-Dihydroxy-ß,k-caroten-6'-one. Capsanthin has a molecular
weight of 584.85
Capsaicin is available in synthetic or natural form. Law enforcement
agencies should be aware of synthetic analogs that are used in order to increase the heat
factor in Capsicum extracts, as well as synthetic or imitation Oleoresin Capsicums. Some
of the known related synthetic capsaicin analogs are:
| N-Vanillyl octanamide |
N-Vanillyl decanamide |
| N-Vanillyl nonanamide |
N-Vanillyl undecanamide |
| N-Vanillyl paaiperic acidamide |
Be aware of synthetic analogues (chemicals) such as n-vanillyl
octanamide used to increase the heat factor in Capsicum extracts to reduce production
costs. These compounds are acidic in nature and can cause serious health hazards and eye
damage.
Capsaicin produces inflammation of the mucous membranes. This is why
those coming into contact with CAP-STUN experience an immediate closing of the eyes,
difficulty in breathing and burning sensation of the skin called REMS.
This neurogenic inflamation is the key difference between
CAP-STUNs effects and other chemical agents and tear-gases.
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