Protective Equipment
An attack with CW agents achieves maximum effect when it is directed
against an unprotected unit. However, by taking relatively simple protective measures, the
injuries can be reduced considerably. In principle, it is possible to create practically
complete CW protection but generally a slightly lower level is considered sufficient. If
the protective level is sufficiently high, an aggressor will probably realize that a CW
attack will not be cost effective.
Effective CW protection requires the building-up of some kind of
"barrier" around the soldier. However, the more the soldier is protected from
the ambient conditions, the greater his mobility is restricted.
Personal Protection
During an attack with CW agents, the respiratory system must be
protected against aerosols and gases in the air at the same time as the rest of the body
must be protected against direct contact with CW agents in the form of liquid or solid
particles. After the attack, the body must be protected against contact with CW agents on
the ground and on equipment. In addition, the respiratory system must be protected against
evaporating gas.
Protection for the Respiratory System
The level of protection provided by a protective mask or respirator
against penetration of biological and chemical weapons through the respiratory system
depends on:
- advance warning,
- time required to don the mask,
- ability of the filter to absorb the CW agent,
- leakage.
CW agents may reach the people on the ground already 5-10 seconds
after an attack. The agents may either be in the form of liquid droplets affecting the
skin or clothing, or as a cloud of gas or aerosol. Already a few breaths from such a cloud
may supply an injurious or lethal dose. In cases of surprise attacks, it is therefore of
vital importance to rapidly don the protective mask so that it fits tightly against the
face.
The best protection against surprise attacks is obtained by
continuously carrying some kind of respiratory protection. A protective mask to be used
for long periods must be comfortable. A solution tested in some countries is a facelet, a
semi-protective mask which is supposed to be more comfortable to wear but does not provide
as good protection as a normal protective ask.
However, experience has shown that the facelet is not a good
alternative and, consequently, efforts are made to make the conventional protective mask
as comfortable as possible to wear. This can be achieved partly by making a broad and
flexible sealing edge and also by reducing the physiological load in the mask.
In modern protective masks, the inhalation resistance has been
reduced by decreasing the air resistance in the filter. Exhalation resistance is reduced
by means of a carefully adjusted outlet valve with a large flow area. Protective masks are
designed so as to reduce the dead space.
Other characteristics of the new generation of protective masks are
a large field of vision and very small leakage, which in turn implies high protection.
Despite this, a small proportion of the wearers will still receive insufficient protection
either because of diverging face shape or inability to don the mask in the best way. This
proportion can be reduced by better training and education but cannot be entirely
eliminated.
A device for speech communication is included in all of the new
masks. The earlier solution, a speech membrane, is now being replaced by a speech horn,
which is easier to manufacture. A speech horn also gives largely the same effect as a
speech membrane. New material for the filter canisters, e.g., fibber-reinforced plastic,
gives them better resistance to external influence.
New technical solutions to the problem of combining protective mask
and glasses are available, which permit correction of visual defects without degrading the
protection.
A protective mask must be capable of adaptation to different face
shapes and is therefore manufactured in an elastic material. Modern masks are almost
always made of some kind of rubber material. If high demands are placed on a good
protective ability to permeation of CW agents, it often results in the choice of
halogenated butyl rubber.
A demand frequently placed today on a protective mask is that it can
be worn for at least 24 hours. The mask must then also permit the intake of liquids.
The filter in a protective mask consists of two parts; an aerosol
filter and a gas filter. The aerosol filter is built up of a layer of glass fibbers where
the spacing between the fibbers is large in relation to the size of the particles to be
filtered. Consequently, an aerosol filter of this kind does not work by screening or
filtering off the particles. The particles are removed mainly when they collide with the
fibbers, to which they adhere. If it is a volatile substance that adheres, it may
subsequently evaporate from the aerosol filter. Consequently, it is important to design a
filter whereby the gas filter component is located after the aerosol filter.
The gas filter component of the protective filter consists of active
carbon. Recently other adsorbents, e.g., different synthetic polymers and zeolites have
been tested but none has proved as widely applicable as active carbon. Neither have any
other absorbents been found to have higher uptake ability for CW agents than active
carbon.
Active carbon is produced by heat-treating different organic
materials. A number of commonly-used materials are peat, coconut shell and coal. The
material is activated by
heating it together with carbon dioxide or steam to 800-1000C. The
carbon so obtained contains numerous pores and cavities and under magnification looks
rather like a face sponge. Active carbon of the type used in protective masks has a total
area of 1 000 -1 500 m2 per gram.
By selecting different starting materials and conducting the
activation in different ways, the active carbon obtained has different degrees of pore
distribution. Carbon with large pores is the most suitable for cleaning water, whereas
carbon with small pores is better for removing gas. Pore distribution and pore size are
also important for the carbon's ability to absorb water. The particle size distribution is
also important and particularly for properties such as air resistance and the protective
ability against different gases.
Certain low-molecular CW agents such as hydrogen cyanide and
cyanogen chloride are poorly absorbed by active carbon. In order to improve protection
against these substances, the carbon is impregnated with metallic salts of copper,
chromium and sometimes also silver. Further impregnation with organic substances also
occurs, the most common additive being triethylendiamine (TEDA).
Certain types of carbon-fibber based material have higher sorption
capacity than normal granulated active carbon. Use of carbon fibbers o this kind in a gas
filter offers advantages such as lower pressure drop, smaller volume and lower weight.
The degree of leakage in modern filters is maximally 0.001 per cent
and, in extreme cases, the filter provides protection against at least 10 but probably up
to 100 attacks before CW agents start to leak through. If the protective mask is used in a
non-contaminated atmosphere the filter will gradually become loaded since it absorbs
moisture and pollution from the air. Long-term use or unsuitable storage may lead to the
protective ability against certain CW agents becoming deteriorate .
Protection Against CW Agents in Liquid Form
A direct CW attack not only results in gases and aerosols but also
droplets of liquid which penetrate the body through the skin. Consequently, respiratory
protection is insufficient and this must be complemented with body protection. The amount
of substance absorbed by the skin is determined by the following factors: CW agent, the
period elapsing before decontamination, the efficiency of the decontaminant, the size of
the contaminated area and he type of clothing.
A condition for high levels of survival after a direct attack with
CW agents in liquid form is either that the entire body surface can rapidly be protected
by some kind of cover, or that protection is incorporated in the uniform of the soldiers.
Protection by covering serves two purposes: it is mainly designed to
prevent droplets falling on bare skin but it is also designed to reduce the need of
subsequent decontamination of personal equipment.
Body Protection
The oldest types of protective clothing against CW agents consists o
rubber clothing which, together with gloves and boots, cover the entire body apart from
that protected by the mask. Clothing of this kind is usually characterized as impermeable.
This not only refers to the fact that CW agents cannot pass through the material but also
the fact that perspiration released from the skin is also prevented from passing out.
Consequently, to wear clothing of this kind for longer periods may be extremely
uncomfortable and in hot climates the period during which protective clothing of this kind
can be worn will be very short.
In order to reduce the heat load, permeable clothing has been
designed where a layer of finely distributed active carbon, either bound in polyurethane
foam or as particles of carbon, is bound between two layers of textile. A layer of this
kind consisting of active carbon permits water vapor released from the body to pass
through. The active carbon absorbs CW agents and thereby prevents them from passing
through to the skin. This layer of carbon is never used alone but is combined with
different textiles.
A CW combat suit is an example of clothing made of permeable
material. It is often designed in the same way as a battle dress. The largest difference
is that inside the impregnated outer material there is a layer of active carbon on a
suitable carrier. The CW combat suit can be used instead of a battle dress or as an
overall placed over the uniform. An alternative is to use inner clothing with a layer of
carbon which is worn underneath the normal uniform. It is impossible to conduct warfare
for longer periods outdoors in CW environment without having access to CW combat suits.
Impermeable suits will also in the future be used in severely
contaminated environments, e.g., during decontamination. The heat load can be reduced by
ventilating the clothing with fans. However, this solution is too vulnerable to be used
for soldiers in combat.
In order to achieve short-term CW protection, it is possible to use
overalls made of different plastic material, e.g., the C-Cover dress.
Development of Protective Masks
The historical development of military protective masks or
respirators may be roughly characterized as four different generations:
- The First World War. The first primitive masks were quickly developed
after the initial use of CW agents during the First World War. The illustration shows an
American mask from 1918. The basic frame of the mask is made of leather.
- The Second World War. The protective capability was greatly improved
during the period between the wars when natural rubber was used to make the basic frame of
the mask. The elastic rubber material allowed the mask to better adapt itself to different
shaped faces.
- After the Second World War and up to about 1980. In about 1950, there
was a more general trend to equip the mask with an inner mask. This must be regarded as a
technical break-through. The inner mask solved the problem with misting of the visors also
in low winter temperatures.
- The current generation of protective masks. During the 1980's and
1990's, protective masks were improved in many ways, as regards for example comfort, fit
and the intake of liquids. It might therefore be justified to regard them as the fourth
generation of protective masks.
Control of Air Flow in a Protective Mask
The inhalation air is first purified during passage through the
filter. The air that has passed through the filter is relatively dry. It is guided up over
the visors in order to prevent them from misting. The flow of air then passes through the
inner mask and then into the lungs. The exhaled air flows directly from the inner mask
through the exhalation valve.
The control of the air flow is achieved by valves. A
well-functioning inhalation valve is essential for the function of the mask. It must allow
air to pass in through the filter but must also prevent the exhaled air from passing out
through the filter. During the inhalation phase, the exhalation valve must be fully closed
and thereby prevent contaminated ambient air from entering the mask by that route.
The task of the inner mask is to prevent the exhaled air from
filling up the entire volume inside the mask. In this way, the moist exhaled air is
prevented from passing over the visors which might cause troublesome condensation. The
inner mask is usually fitted with valves to control the air flow. However, it is fully
possible to design a functional inner mask without any valves.
Fitting Protective Masks
A measure of the protective ability of a mask is given by the total
inward leakage. This consists of the sum of the leakage in the filter, the leakage through
the fit, leakage through the exhalation valve and any other leakage. Instead, the
protection factor of the mask is frequently given:
Protection factor = (Concentration of a contaminant in the ambient
air) / (Concentration of the same contaminant inside the mask)
The protection factor states how much lower the concentration of a
pollutant in the air is inside the mask in comparison with the concentration in the
ambient air. Laboratory tests with a non-hazardous test substance can easily determine
protection factors up to 100 000. In the field, tear gas can be used as a test substance
to obtain a rough measure of the protective ability of a mask. The sensitivity in tests
with tear gas (CS) is, however, not larger than that it corresponds to a protection factor
somewhere in the range between 1 000 and 10 000.
Even in a modern mask with a good sealing edge, the fit will start
to deteriorate already when the soldier has a 24 h-old beard stubble. The protection will
deteriorate with the length of the stubble. Whole beards usually result in very poor
protection.
Penetration and Permeation
Two special terms are used with regard to protective clothing,
penetration and permeation. Penetration implies that gases or liquids pass through seams
or holes, etc. in a protective suit (non-molecular passage). Permeation implies that gases
or liquids diffuse through the material, e.g., rubber, in a protective suit (molecular
passage).
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