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DM
Diphenylaminochlorarsine (Dinhydrophenarsazine)

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Color Code: |
Green |
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Agent State: |
Micro-Particulate Solid |
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Classification: |
Micro-Particulate Solid |
| Chemical: |
- Synthetic, contains about 27 per cent arsenic
- Developed in 1913
- LC50: Lethal at 1500 mg/m3 for 10 minutes
- Takes effects in 6 minutes
- Produces: Watery nasal discharge, sneezing
Severe pain in nose and chest
Nausea, vomiting
Sensory disturbances
- May result in death
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Agent DM was developed by the American
chemist Roger Adams of the US Chemical Warfare Division during World War I as an
improvement on diphenylchlorarsine, the latter having been introduced by the Germans in
1913. DM is commonly called "adamsite" or "vomiting Gas". It contains
about 27 per cent arsenic. On re-crystallization from benzene-glacial acetic acid, DM is a
yellow solid with essentially no odor. It is an irritant at a concentration of a fraction
of a milligram per cubic meter and is believed to be lethal at 1500 mg/m3 for 10 minutes
exposure. The agent DM is prepared by mixing diphenylamine with arsenic trichloride. The
product used in chemical munitions is grossly impure and contains a variety of
contaminants. According to the authoritative Merck Index, Vol. 8, Page 804, 1968, DM
causes ". . . profuse watery nasal discharge; severe pain in nose and chest;
sneezing, coughing, nausea, vomiting, depression, weakness. Sensory disturbances may
occur."
It takes about six minutes for DM to take effect, therefore, CN
(Chloroacetophenone) is mixed with DM in order to start the action on the eyes
immediately. Shortly after, the individual starts violent sneezing and coughing and the
solid particles of the chemical settle in the lungs. A subject will lose complete control
of himself. Severe headaches, vomiting and nausea similar to a severe state of seasickness
are present and the effects are so much longer lasting and often so severe that medical
treatment is required. DM is capable of poisoning water and open foodstuffs in the areas
that are affected. Due to DMs severe and fatal effects, at the present almost no
agency is adopting this agent any longer.
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